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Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic self-cleaning

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1450-1459 doi: 10.1007/s11705-023-2310-3

摘要: Membrane technology is ideal for removing aqueous humic acid, but humic acid deposits cause membrane fouling, a significant challenge that limits its application. Herein, this work proposed an alternative approach to the controllably magnetically induced magneto-hybrid polyoxometalate (magneto-HPOM) nanocomposite migration toward the polyethersulfone (PES) membrane surface under a magnetic field to enhance the self-cleaning and antifouling functionalities of the membrane. Before incorporating magneto-HPOM nanocomposite into the PES casting solution, functionalized magnetite nanoparticles (F-MNP) were first coated with HPOM photocatalyst to fabricate a magneto-HPOM-PES membrane. It was shown that the apparent impacts of this novel magneto-HPOM-PES membrane on the hydrophilic behavior and photocatalytic properties of the magneto-HPOM nanocomposite improve the hydrophilicity, separation performance, antifouling and self-cleaning properties of the membrane compared with neat PES membrane. Furthermore, after exposure to ultraviolet light, the magneto-HPOM-PES membrane can be recovered after three cycles with a flux recovery ratio of 107.95%, 100.06%, and 95.56%, which is attributed to the temporal super hydrophilicity effect. Meanwhile, the magneto-HPOM-PES membrane could efficiently maintain 100% humic acid rejection for the first and second cycles and 99.81% for the third cycle. This study revealed a novel approach to fabricating membranes with high antifouling and self-cleaning properties for water treatment.

关键词: magneto-hybrid polyoxometalate nanocomposite     composite membrane     antifouling     self-cleaning     magnetic and photocatalytic responsiveness    

Formation of disinfection by-products during sodium hypochlorite cleaning of fouled membranes from membrane

《环境科学与工程前沿(英文)》 2021年 第15卷 第5期 doi: 10.1007/s11783-021-1389-3

摘要:

•HAAs was dominant among the DBPs of interest.

关键词: MBR     Biofouling     EPS     Chemical cleaning     DBPs     CLSM    

一种新型的多功能油——清洁润滑防护武器三用油

冯薇荪,汪孟言

《中国工程科学》 2000年 第2卷 第4期   页码 53-58

摘要:

武器三用油是一种不同于传统润滑油的油品。它不仅功能多,而且性能优异,可供陆、海、空三军在各种不同气候条件下使用;也可以广泛用于车辆、船舶、工厂、建筑物等民用设施。由于一种油品同时要具备多种功能,因此必需精心设计配方,考虑不同基础油及各种添加剂的配伍性,扬长避短,发挥增效作用,避免不利因素。在三用油研制过程中,考察了各种影响因素,将矛盾的各个方面很好地统一在一个油品中,获得了能满足各项要求的清洁、润滑、防护武器三用油。

关键词: 武器三用油     基础油     添加剂     清洁     润滑     防护    

A thermodynamic study of the removal of HCl and H

Joseph LEE, Bo FENG

《化学科学与工程前沿(英文)》 2012年 第6卷 第1期   页码 67-83 doi: 10.1007/s11705-011-1162-4

摘要: Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IFGC) systems require high-temperature sorbents that are capable of removing hydrogen chloride and hydrogen sulfide from coal derived gases to very low levels. HCl and H S are highly reactive, corrosive, and toxic gases that must be removed to meet stringent environmental regulations, to protect power generation equipment and to control the emissions of contaminants. The thermodynamic behavior of 13 sorbents for the removal of HCl and H S under various conditions including: initial toxic gas concentration (1–10000 ppm), operating pressure (0.1–11 Mpa), temperature (300 K–1500 K), and the presence of H O were investigated. The correlation between HCl and H S was also examined. Thermodynamic calculations were carried out for the reactions of the 13 sorbents using a FactSage 5.2 software package based on free energy minimization. The sorbents, Na CO , NaHCO , K CO , and CaO are capable of completely removing chlorine at high temperatures (up to ~1240 K) and at high pressures. Water vapor did not have any significant effects on the dechlorination capability of the sorbents. Nine of the sorbents namely; Cu O, Na CO , NaHCO , K CO , CaO, ZnO, MnO, FeO, and PbO, were determined to have great potential as desulfurization sorbents. Cu O and ZnO had the best performance in terms of the optimum operating temperature. The addition of water vapor to the reactant gas produces a slightly detrimental effect on most of the sorbents, but FeO exhibited the worst performance with a reduction in the maximum operating temperature of about 428 K. The dechlorination performance of the alkali sorbents was not affected by the presence of H S in the reactions. However, the desulfurization capability of some sorbents was greatly affected by the presence of HCl. Particularly, the performance of Cu O was significantly reduced when HCl was present, but the performance of FeO improved remarkably. The thermodynamic results gathered are valuable for the developments of better sorbents.

关键词: syngas cleaning     sorbent     desulfurization     dechlorination    

Using loose nanofiltration membrane for lake water treatment: A pilot study

《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1362-6

摘要:

• A pilot study was conducted for drinking water treatment using loose NF membranes.

关键词: Nanofiltration     Drinking water     Membrane fouling     Aluminum carryover     Chemical cleaning    

Exploring self-organization and self-adaption for smart manufacturing complex networks

《工程管理前沿(英文)》 2023年 第10卷 第2期   页码 206-222 doi: 10.1007/s42524-022-0225-1

摘要: Trends toward the globalization of the manufacturing industry and the increasing demands for small-batch, short-cycle, and highly customized products result in complexities and fluctuations in both external and internal manufacturing environments, which poses great challenges to manufacturing enterprises. Fortunately, recent advances in the Industrial Internet of Things (IIoT) and the widespread use of embedded processors and sensors in factories enable collecting real-time manufacturing status data and building cyber–physical systems for smart, flexible, and resilient manufacturing systems. In this context, this paper investigates the mechanisms and methodology of self-organization and self-adaption to tackle exceptions and disturbances in discrete manufacturing processes. Specifically, a general model of smart manufacturing complex networks is constructed using scale-free networks to interconnect heterogeneous manufacturing resources represented by network vertices at multiple levels. Moreover, the capabilities of physical manufacturing resources are encapsulated into virtual manufacturing services using cloud technology, which can be added to or removed from the networks in a plug-and-play manner. Materials, information, and financial assets are passed through interactive links across the networks. Subsequently, analytical target cascading is used to formulate the processes of self-organizing optimal configuration and self-adaptive collaborative control for multilevel key manufacturing resources while particle swarm optimization is used to solve local problems on network vertices. Consequently, an industrial case based on a Chinese engine factory demonstrates the feasibility and efficiency of the proposed model and method in handling typical exceptions. The simulation results show that the proposed mechanism and method outperform the event-triggered rescheduling method, reducing manufacturing cost, manufacturing time, waiting time, and energy consumption, with reasonable computational time. This work potentially enables managers and practitioners to implement active perception, active response, self-organization, and self-adaption solutions in discrete manufacturing enterprises.

关键词: cyber–physical systems     Industrial Internet of Things     smart manufacturing complex networks     self-organization and self-adaption     analytical target cascading     collaborative optimization    

Emerging trends in self-healable nanomaterials for triboelectric nanogenerators: A comprehensive review

《能源前沿(英文)》   页码 727-750 doi: 10.1007/s11708-023-0896-2

摘要: A thorough analysis of triboelectric nanogenerators (TENGs) that make use of self-healable nanomaterials is presented in this review. These TENGs have shown promise as independent energy sources that do not require an external power source to function. TENGs are developing into a viable choice for powering numerous applications as low-power electronics technology advances. Despite having less power than conventional energy sources, TENGs do not directly compete with these. TENGs, on the other hand, provide unique opportunities for future self-powered systems and might encourage advancements in energy and sensor technologies. Examining the many approaches used to improve nanogenerators by employing materials with shape memory and self-healable characteristics is the main goal of this review. The findings of this comprehensive review provide valuable information on the advancements and possibilities of TENGs, which opens the way for further research and advancement in this field. The discussion of life cycle evaluations of TENGs provides details on how well they perform in terms of the environment and identifies potential improvement areas. Additionally, the cost-effectiveness, social acceptability, and regulatory implications of self-healing TENGs are examined, as well as their economic and societal ramifications.

关键词: triboelectric nanogenerator (TENG)     self-healable nanomaterials     self-powered devices     energy    

Modular structure of a self-reconfigurable robot

FEI Yanqiong, DONG Qinglei, ZHAO Xifang

《机械工程前沿(英文)》 2007年 第2卷 第1期   页码 116-119 doi: 10.1007/s11465-007-0020-z

摘要: This paper proposes a novel, hermaphroditic, and lattice self-reconfigurable modular robot. Each module is composed of a center body a cubic part and six sides that can rotate independently. There are two holes and two extensible pegs on each side. The rotary motion of each side and the extensible motion of the pegs are generated by a motor connected to a reducer, using a cone-shaped gear, belt, clutch, etc. The structure of the module is compact, and has space to extend further.

关键词: compact     self-reconfigurable modular     hermaphroditic     cone-shaped     clutch    

Signal separation technology for diphase opposition giant magnetostrictive self-sensing actuator

Xinhua WANG, Shuwen SUN, Jian ZHEN, Qianyi YA, Deguo WANG,

《机械工程前沿(英文)》 2010年 第5卷 第2期   页码 176-183 doi: 10.1007/s11465-010-0001-5

摘要: The structure and principle of a new type of a diphase opposition giant magnetostrictive self-sensing actuator is introduced. A bridge analysis model based on variable inductance is established. Dynamic balance separation technology for the giant magnetostrictive self-sensing actuator comes true by the least means square (LMS) self-adapting algorithm. The scheme design of one important part of the circuit with the real-time separation circuit of the dynamic balance signal based on a digital signal processor is obtained. The part of the signal separated circuit is designed, which includes logarithmic-antilog practical multiplication circuit, amplifying circuit, filter circuits, and amplifier circuit. Based on the embedded system simulation software—PROTUES, the simulation effect of the circuit that separates the sensing signal from the mixed signals is obvious, which indicates that the circuit can rapidly and stably work. Moreover, the structure is simple, reliable, and meets the practical requirement.

关键词: giant magnetostrictive material (GMM) self-sensing actuator     least means square (LMS) self-adapting algorithm     design of self-adaptive circuit    

Behaviour of self-centring shear walls——A state of the art review

《结构与土木工程前沿(英文)》 2023年 第17卷 第1期   页码 53-77 doi: 10.1007/s11709-022-0850-0

摘要: The application of unbonded post-tensioning (PT) in structural walls has led to the development of advanced self-centring (rocking) shear wall systems that has significant advantages, including accelerated construction due to the incorporation of prefabricated elements and segmental construction for different materials (e.g., concrete, masonry, and timber), reduced residual drifts, and little damage upon extreme seismic and wind loads. Concrete, masonry, and timber are often used for the construction of unbonded PT structural wall systems. Despite extensive research since the 1980s, there are no well-established design guidelines available on the shear wall configuration with the required energy dissipation system, joint’s locations and acceptance criteria for shear sliding, confinement, seismic performance factors, PT loss, PT force range and residual drifts of shear walls subjected to lateral loads. In this research a comprehensive state-of-the-art literature review was performed on self-centring shear wall system. An extensive study was carried out to collect a database of 100 concrete, masonry, and self-centring shear wall tests from the literature. The established database was then used to review shear walls’ configurations, material, and components to benchmark requirements applicable for design purposes. The behaviour of concrete, masonry and timber shear walls were compared and critically analysed. The general behaviour, force-displacement performance of the walls, ductility, and seismic response factors, were critically reviewed and analysed for different self-centring wall systems to understand the effect of different parameters including configurations of the walls, material used for construction of the wall (concrete, masonry, timber) and axial stress ratio. The outcome of this research can be used to better understand the behaviour of self-centring wall system in order to develop design guidelines for such walls.

关键词: self-centring shear walls     rocking walls     energy dissipation     seismic performance factors     PT loss     residual drift    

Recycled glass replacement as fine aggregate in self-compacting concrete

Yasser SHARIFI, Mahmoud HOUSHIAR, Behnam AGHEBATI

《结构与土木工程前沿(英文)》 2013年 第7卷 第4期   页码 419-428 doi: 10.1007/s11709-013-0224-8

摘要: With increasing environmental pressure to reduce solid waste and to recycle as much as possible, the concrete industry has adopted a number of methods to achieve this goal by replacement of waste glass with concrete composition materials. Due to differences in mixture design, placement and consolidation techniques, the strength and durability of Self Compacting Concrete (SCC) may be different than those of conventional concrete. Therefore, replacement of waste glass with fine aggregate in SCC should deeply be investigated compared to conventional concretes. The aim of the present study is to investigate the effect of glass replacement with fine aggregate on the SCC properties. In present study, fine aggregate has been replaced with waste glass in six different weight ratios ranging from 0% to 50%. Fresh results indicate that the flow-ability characteristics have been increased as the waste glass incorporated to paste volume. Nevertheless, compressive, flexural and splitting strengths of concrete containing waste glass have been shown to decrease when the content of waste glass is increased. The strength reduction of concrete in different glass replacement ratios is not remarkable, thus it can be produced SCC with waste glass as fine aggregate in a standard manner.

关键词: Self Compacting Concrete (SCC)     recycle glass     fine aggregate     fresh and hardened properties    

Effect of calcium lactate on compressive strength and self-healing of cracks in microbial concrete

Kunamineni VIJAY, Meena MURMU

《结构与土木工程前沿(英文)》 2019年 第13卷 第3期   页码 515-525 doi: 10.1007/s11709-018-0494-2

摘要: This paper presents the effect on compressive strength and self-healing capability of bacterial concrete with the addition of calcium lactate. Compared to normal concrete, bacterial concrete possesses higher durability and engineering concrete properties. The production of calcium carbonate in bacterial concrete is limited to the calcium content in cement. Hence calcium lactate is externally added to be an additional source of calcium in the concrete. The influence of this addition on compressive strength, self-healing capability of cracks is highlighted in this study. The bacterium used in the study is and was added to both spore powder form and culture form to the concrete. spore powder of 2 million cfu/g concentration with 0.5% cement was mixed to concrete. Calcium lactates with concentrations of 0.5%, 1.0%, 1.5%, 2.0%, and 2.5% of cement, was added to the concrete mixes to test the effect on properties of concrete. In other samples, cultured with a concentration of 1×10 cells/mL was mixed with concrete, to study the effect of bacteria in the cultured form on the properties of concrete. Cubes of 100 mm×100 mm×100 mm were used for the study. These cubes were tested after a curing period of 7, 14 and 28 d. A maximum of 12% increase in compressive strength was observed with the addition of 0.5% of calcium lactate in concrete. Scanning electron microscope and energy dispersive X-ray spectroscopy examination showed the formation of ettringite in pores; calcium silicate hydrates and calcite which made the concrete denser. A statistical technique was applied to analyze the experimental data of the compressive strengths of cementations materials. Response surface methodology was adopted for optimizing the experimental data. The regression equation was yielded by the application of response surface methodology relating response variables to input parameters. This method aids in predicting the experimental results accurately with an acceptable range of error. Findings of this investigation indicated the influence of added calcium lactate in bio-concrete which is quite impressive for improving the compressive strength and self-healing properties of concrete.

关键词: calcium lactate     bacillus subtilis     compressive strength     self-healing of cracks    

铸钢粗晶的成因及消除方法的研究

邹安全,邓沛然

《中国工程科学》 2005年 第7卷 第4期   页码 79-82

摘要:

通过对ZG32Cr06铸钢粗晶成因的分析及消除粗晶的工艺性能试验,探讨了粗晶导致铸件断裂的机理。试验证明,由于浇铸温度过高,水爆清砂时开箱过早而产生的粗晶可以用热处理方法消除,同时提出了铸件在浇铸时防止粗晶的措施。

关键词: 铸钢     粗晶     水爆清砂     消除方法    

Computational fluid dynamic analysis of flutter characteristics for self-anchored suspension bridges

ZHU Zhiwen, WANG Zhaoxiang, CHEN Zhengqing

《结构与土木工程前沿(英文)》 2008年 第2卷 第3期   页码 267-273 doi: 10.1007/s11709-008-0034-6

摘要: This paper outlines the essentials and procedures of computational fluid dynamics (CFD) simulation applicable to evaluating flutter derivatives of bridge decks. An arbitrary Lagrangian-Eulerian (ALE) description of the flow around the moving rigid box girder combined with the finite volume discretization and multi-grid algorithm is presented. The proposed methods are employed to identify flutter derivatives of the bridge deck of the Sanchaji Self-anchored Suspension Bridge. The results agree well with ones from wind tunnel tests. It demonstrates accuracy and efficiency of the present method.

关键词: discretization     computational     description     Self-anchored Suspension     simulation applicable    

Effects of solvents and temperature on spherulites of self-assembled phloroglucinol tristearate

Yawen Yao, Sabine Rosenfeldt, Kai Zhang

《化学科学与工程前沿(英文)》 2020年 第14卷 第3期   页码 389-396 doi: 10.1007/s11705-019-1911-3

摘要: Herein, phloroglucinol tristearate (PhgTS) was used to study the crystallization process due to its unique symmetric structure containing a benzene ring and three aliphatic chains. Spherulites of crystallized PhgTS from four solvents under diverse conditions were analyzed in detail and their formation process was studied. Maltese cross is shown by PhgTS spherulites obtained from aprotic solvents via polarized optical microscopy. In comparison, no Maltese cross can be observed from branch-like crystals formed from protic solvents. Independent on the microscaled morphology, lamellae were found to be the basic blocks constructing both PhgTS spherulites and branch-like crystals, which were formed predominantly by stacked PhgTS molecules. Although differential characters of the solvents did not affect the formation of lamellas, the solvents played a crucial role in the formation of self-assembled microscaled morphologies. In particular, the morphologies of spherulites were strongly affected by the concentration of PhgTS solutions, surrounding temperature and evaporation rate of solvents. Generally, a higher concentration of PhgTS led to more homogeneous spherulites, a lower evaporation rate resulted in more compact spherulites, and a higher surrounding temperature generated preferentially more ring-banded spherulites of PhgTS.

关键词: phloroglucinol     tristearate     aprotic and protic solvent     self-assembly     spherulites    

标题 作者 时间 类型 操作

Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic self-cleaning

期刊论文

Formation of disinfection by-products during sodium hypochlorite cleaning of fouled membranes from membrane

期刊论文

一种新型的多功能油——清洁润滑防护武器三用油

冯薇荪,汪孟言

期刊论文

A thermodynamic study of the removal of HCl and H

Joseph LEE, Bo FENG

期刊论文

Using loose nanofiltration membrane for lake water treatment: A pilot study

期刊论文

Exploring self-organization and self-adaption for smart manufacturing complex networks

期刊论文

Emerging trends in self-healable nanomaterials for triboelectric nanogenerators: A comprehensive review

期刊论文

Modular structure of a self-reconfigurable robot

FEI Yanqiong, DONG Qinglei, ZHAO Xifang

期刊论文

Signal separation technology for diphase opposition giant magnetostrictive self-sensing actuator

Xinhua WANG, Shuwen SUN, Jian ZHEN, Qianyi YA, Deguo WANG,

期刊论文

Behaviour of self-centring shear walls——A state of the art review

期刊论文

Recycled glass replacement as fine aggregate in self-compacting concrete

Yasser SHARIFI, Mahmoud HOUSHIAR, Behnam AGHEBATI

期刊论文

Effect of calcium lactate on compressive strength and self-healing of cracks in microbial concrete

Kunamineni VIJAY, Meena MURMU

期刊论文

铸钢粗晶的成因及消除方法的研究

邹安全,邓沛然

期刊论文

Computational fluid dynamic analysis of flutter characteristics for self-anchored suspension bridges

ZHU Zhiwen, WANG Zhaoxiang, CHEN Zhengqing

期刊论文

Effects of solvents and temperature on spherulites of self-assembled phloroglucinol tristearate

Yawen Yao, Sabine Rosenfeldt, Kai Zhang

期刊论文